Pine Oil<\/p>\n
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION <\/i><\/b><\/p>\n
Product name : Pine OIl <\/p>\n
Company <\/p>\n
REFLECTA LAB SUPPLIES <\/p>\n
SECTION 2 Pine Oil \ufffd\ufffd\ufffd HAZARDS IDENTIFICATION <\/i><\/b>GHS-Classification <\/b><\/p>\n
Flammable liquids, Category 4 <\/p>\n
Skin irritation, Category 2 <\/p>\n
Eye irritation, Category 2A <\/p>\n
Skin sensitisation, Category 1 <\/p>\n
Aspiration hazard, Category 1 <\/p>\n
GHS-Labelling <\/b><\/p>\n
Symbol(s) : <\/p>\n
Signal word : Danger<\/p>\n
Pine Oil <\/b><\/p>\n
Hazard statements : H227: Combustible liquid. <\/p>\n
H304: May be fatal if swallowed and enters airways. <\/p>\n
H315: Causes skin irritation. <\/p>\n
H317: May cause an allergic skin reaction. <\/p>\n
H319: Causes serious eye irritation. <\/p>\n
Precautionary statements : P210: Keep away from heat\/sparks\/open flames\/hot surfaces. No smoking. <\/p>\n
P280: Wear protective gloves\/ eye protection\/ face protection. <\/p>\n
P301 + P310: IF SWALLOWED: Immediately call a POISON <\/p>\n
CENTER or doctor\/ physician. <\/p>\n
P302 + P352: IF ON SKIN: Wash with plenty of soap and water. <\/p>\n
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for <\/p>\n
several minutes. Remove contact lenses, if present and easy to do. <\/p>\n
Continue rinsing. <\/p>\n
P331: Do NOT induce vomiting. <\/p>\n
Carcinogenicity: <\/b><\/p>\n
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. <\/p>\n
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. <\/p>\n
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. <\/p>\n
SECTION 3. COMPOSITION\/INFORMATION ON INGREDIENTS <\/i><\/b>Chemical nature : Fragrance for consumer product <\/p>\n
Hazardous components<\/p>\n
| Component <\/b><\/td>\n | CAS-No.<\/b><\/td>\n<\/tr>\n| Oils, pine <\/td>\n | 8002-09-3, 8000-41-7<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n | Pine Oil <\/b><\/p>\n SECTION 4. Pine Oil \ufffd\ufffd\ufffd FIRST AID MEASURES <\/i><\/b><\/p>\n First aid procedures <\/b><\/p>\n Inhalation : Remove from exposure site to fresh air and keep at rest. If victim is unconscious, remove foreign bodies from the mouth. If victim has <\/p>\n stopped breathing, give artificial respiration. Obtain medical advice. <\/p>\n Skin contact : Remove contaminated clothes. Wash thoroughly with water (and soap). Contact physician if symptoms persist. <\/p>\n Eye contact : Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. <\/p>\n Ingestion : Rinse mouth with water and obtain medical advice. <\/p>\n SECTION 5. FIREFIGHTING MEASURES <\/i><\/b><\/p>\n Flammable properties <\/b><\/p>\n Flash point : 162 \ufffd\ufffdF (72 \ufffd\ufffdC) <\/p>\n Fire fighting <\/b><\/p>\n Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate foam. Protective equipment and precautions for firefighters <\/b> Special protective equipment for firefighters <\/p>\n : Wear NIOSH approved self-contained breathing apparatus and full protective clothing when fighting fires involving chemicals. Use water spray to cool containers exposed to fire. <\/p>\n Pine Oil <\/b><\/p>\n SECTION 6. ACCIDENTAL RELEASE MEASURES <\/i><\/b><\/p>\n Personal precautions : Avoid inhalation and contact with skin and eyes. A self-contained breathing apparatus is recommended in case of a major spill. <\/p>\n Environmental precautions : Keep away from drains, surface- and groundwater and soil. <\/p>\n Methods for containment \/ : Clean up spillage promptly. Remove ignition sources. Provide Methods for cleaning up adequate ventilation. Avoid excessive inhalation of vapours. Gross spillages should be contained by use of sand or inert powder <\/p>\n and disposed of according to the local regulations. <\/p>\n SECTION 7. Pine Oil \ufffd\ufffd\ufffd HANDLING AND STORAGE <\/i><\/b> Handling <\/p>\n Advice on protection against fire and explosion <\/p>\n : Avoid excessive inhalation of concentrated vapors. Follow good manufacturing practices for housekeeping and personal hygiene. Wash any exposed skin immediately after any chemical contact, before breaks and meals, and at the end of each work period. <\/p>\n Contaminated clothing and shoes should be thoroughly cleaned before re-use. <\/p>\n If appropriate, procedures used during the handling of this material should also be used when cleaning equipment or removing residual chemicals from tanks or other containers, especially when steam or hot water is used, as this may increase vapor concentrations in the <\/p>\n workplace air. Where chemicals are openly handled, access should be restricted to properly trained employees. <\/p>\n Keep all heated processes at the lowest necessary temperature in order to minimize emissions of volatile chemicals into the air. <\/p>\n : Keep away from ignition sources and naked flame.<\/p>\n Requirements for storage areas and containers <\/p>\n Pine Oil <\/b><\/p>\n : Store in a cool, dry, ventilated area away from heat sources. Keep containers upright and tightly closed when not in use. <\/p>\n SECTION 8. EXPOSURE CONTROLS\/PERSONAL PROTECTION <\/i><\/b>Components with workplace control parameters <\/b><\/p>\n limit(s)<\/p>\n<\/td>\n<\/tr>\n .alpha.,.alpha.,4- <\/p>\n trimethyl <\/p>\n<\/td>\n methyl-4-(1- <\/p>\n methylethenyl)-, <\/p>\n Cyclohexene, 1- <\/p>\n methyl-4-(1- <\/p>\n methylethenyl)-, <\/p>\n (4R)-, Cyclohexene, 1-methyl-4-(1- <\/p>\n methylethenyl)-, <\/p>\n (4S)-<\/p>\n<\/td>\n Engineering measures <\/b><\/p>\n Engineering measures : Where feasible, isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under <\/p>\n negative air pressure relative to the rest of the plant. <\/p>\n Where feasible, use closed systems to transfer and process this <\/p>\n material <\/p>\n Personal protective equipment <\/b><\/p>\n Eye protection : Use tight-fitting goggles, face shield or safety glasses with side<\/p>\n Pine Oil <\/b><\/p>\n shields if eye contact might occur. <\/p>\n Hand protection : Avoid skin contact. Use chemically resistant gloves. <\/p>\n Respiratory protection : Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, <\/p>\n including places where this material is openly weighed or measured. <\/p>\n In addition, use general dilution ventilation of the work area to <\/p>\n eliminate or reduce possible worker exposures. <\/p>\n No respiratory protection is required during normal operations in a <\/p>\n workplace where engineering controls such as adequate ventilation, <\/p>\n etc. are sufficient. <\/p>\n If engineering controls and safe work practices are not sufficient, an <\/p>\n approved, properly fitted respirator with organic vapor cartridges or <\/p>\n canisters and particulate filters should be used: <\/p>\n a)while engineering controls and appropriate safe work practices <\/p>\n and\/or procedures are being implemented; or <\/p>\n b)during short term maintenance procedures when engineering <\/p>\n controls are not in normal operation or are not sufficient; or <\/p>\n c)if normal operational workplace vapor concentration in the air is <\/p>\n increased due to heat ; <\/p>\n d)during emergencies; or <\/p>\n e)if engineering controls and operational practices are not sufficient <\/p>\n to reduce airborne concentrations below an established occupational <\/p>\n exposure limit. <\/p>\n Hygiene measures : To the extent deemed appropriate, implement pre-placement and regularly scheduled ascertainment of symptoms and spirometry <\/p>\n testing of lung function for workers who are regularly exposed to <\/p>\n this material. <\/p>\n To the extent deemed appropriate, use an experienced air sampling <\/p>\n expert to identify and measure volatile chemicals that could be <\/p>\n present in the workplace air to determine potential exposures and to <\/p>\n ensure the continuing effectiveness of engineering controls and <\/p>\n operational practices to minimize exposure.<\/p>\n Pine Oil <\/b><\/p>\n Protective measures : In December 2003, the National Institute for Occupational Safety and Health (\ufffd\ufffd\ufffdNIOSH\ufffd\ufffd\ufffd) published an Alert on preventing lung <\/p>\n disease in workers who use or make flavorings [NIOSH Publication <\/p>\n Number 2004-110]. <\/p>\n In August 2004, the United States Flavor and Extract Manufacturers <\/p>\n Association (FEMA) issued a report entitled \ufffd\ufffd\ufffdRespiratory Safety in <\/p>\n the Flavor Manufacturing Workplace\ufffd\ufffd\ufffd. <\/p>\n Both of these reports provide recommendations for reducing <\/p>\n employee exposure and for medical surveillance in the workplace. <\/p>\n The recommendations in these reports are generally applicable to the <\/p>\n use of any chemical in the workplace and you are strongly urged to <\/p>\n review both of these reports. <\/p>\n The report published by FEMA also contains a list of \ufffd\ufffd\ufffdhigh priority\ufffd\ufffd\ufffd <\/p>\n chemicals. If any of these chemicals are present in this product at a <\/p>\n concentration >= 1.0% due to an intentional addition by IFF, the <\/p>\n chemical(s) will be identified in this safety data sheet. <\/p>\n SECTION 9. Pine Oil \ufffd\ufffd\ufffd PHYSICAL AND CHEMICAL PROPERTIES <\/i><\/b><\/p>\n Appearance <\/b><\/p>\n Physical state : liquid <\/p>\n Appearance : CLEAR LIQUID <\/p>\n Colour : colorless to pale yellow <\/p>\n Odour : conforms to standard <\/p>\n Safety data <\/b><\/p>\n Flash point : 162 \ufffd\ufffdF (72 \ufffd\ufffdC) <\/p>\n Vapour pressure : 5.33 hPa (5.33 hPa) <\/p>\n Note: Calculated<\/p>\n Pine Oil <\/b><\/p>\n Relative density (20 \ufffd\ufffdC) : 0.9240 \ufffd\ufffd\ufffd 0.9310 <\/p>\n SECTION 10. STABILITY AND REACTIVITY <\/i><\/b>Conditions to avoid : Remarks: Direct sources of heat. <\/p>\n Chemical stability : Remarks: Presents no significant reactivity hazard, by itself or in contact with water. Avoid contact with strong acids, alkali or <\/p>\n oxidizing agents. <\/p>\n Hazardous decomposition products : Note: Carbon monoxide and unidentified organic compounds may be formed during combustion. <\/p>\n SECTION 11. TOXICOLOGICAL INFORMATION <\/i><\/b><\/p>\n Acute oral toxicity : Acute toxicity estimate <\/p>\n Dose: 2,027 mg\/kg <\/p>\n Method: Calculation method <\/p>\n Acute oral toxicity (Component) : Component: 98-55-5 <\/p>\n LD50 Rat <\/p>\n Dose: 4,300 mg\/kg <\/p>\n Method: OECD Test Guideline 401 <\/p>\n Remarks: RIFM <\/p>\n Component: 138-86-3 <\/p>\n LD50 Rat <\/p>\n Dose: 5,300 mg\/kg <\/p>\n Component: 586-62-9 <\/p>\n LD50 Rat <\/p>\n Dose: 3,840 mg\/kg<\/p>\n Pine Oil <\/b><\/p>\n Remarks: RIFM <\/p>\n Component: 562-74-3 <\/p>\n LD50 Rat <\/p>\n Dose: 1,300 mg\/kg <\/p>\n Remarks: RIFM <\/p>\n Component: 470-82-6 <\/p>\n LD50 Rat <\/p>\n Dose: 2,480 mg\/kg <\/p>\n Remarks: Supplier <\/p>\n Acute dermal toxicity : Acute toxicity estimate Dose: 3,733 mg\/kg <\/p>\n Method: Calculation method <\/p>\n Acute dermal <\/p>\n toxicity (Component) <\/p>\n : Component: 98-55-5 <\/p>\n LD50 Rabbit <\/p>\n Dose: > 3,000 mg\/kg <\/p>\n Method: OECD Test Guideline 402 <\/p>\n Component: 138-86-3 <\/p>\n LD50 Rabbit <\/p>\n Dose: > 5,000 mg\/kg <\/p>\n Component: 586-62-9 <\/p>\n LD50 Rabbit <\/p>\n Dose: > 5,000 mg\/kg <\/p>\n Component: 562-74-3 <\/p>\n LD50 Rabbit <\/p>\n Dose: 2,500 mg\/kg <\/p>\n Component: 470-82-6 <\/p>\n LD50 Rabbit <\/p>\n Dose: > 5,000 mg\/kg <\/p>\n Pine Oil <\/b><\/p>\n Skin irritation (Component) : Component: 98-55-5 Rabbit <\/p>\n Result: Skin irritation <\/p>\n Method: OECD Test Guideline 404 <\/p>\n Exposure time: 24 h <\/p>\n Component: 138-86-3 <\/p>\n Rabbit <\/p>\n Result: Skin irritation <\/p>\n Exposure time: 24 h <\/p>\n Test substance:(undiluted) <\/p>\n human <\/p>\n Result: No skin irritation <\/p>\n Method: closed patch test <\/p>\n Exposure time: 48 h <\/p>\n Component: 586-62-9 <\/p>\n human <\/p>\n Result: No skin irritation <\/p>\n Method: closed patch test <\/p>\n Exposure time: 48 h <\/p>\n Rabbit <\/p>\n Result: No skin irritation <\/p>\n Exposure time: 24 h <\/p>\n Component: 562-74-3 <\/p>\n Rabbit <\/p>\n Result: Skin irritation <\/p>\n Exposure time: 24 h <\/p>\n Component: 470-82-6 <\/p>\n Rabbit <\/p>\n Result: No skin irritation <\/p>\n Exposure time: 24 h <\/p>\n Eye irritation(Component) : Component: 98-55-5 Rabbit<\/p>\n Pine Oil <\/b><\/p>\n Result: Eye irritation <\/p>\n Method: OECD Test Guideline 405 <\/p>\n Exposure time: 72 h <\/p>\n Sensitisation (Component) : Component: 98-55-5 <\/p>\n LLNA Rat <\/p>\n Result: causes no sensitization <\/p>\n Method: OECD Test Guideline 429 <\/p>\n Component: 138-86-3 <\/p>\n LLNA Mouse <\/p>\n Result: Causes sensitisation. <\/p>\n Test substance: 22% in ethanol\/DEP (75:25) <\/p>\n maximisation study human <\/p>\n Result: causes no sensitization <\/p>\n Test substance: 20% in petrolatum <\/p>\n Component: 586-62-9 <\/p>\n maximisation study human <\/p>\n Result: Did not cause sensitisation on laboratory animals. <\/p>\n Test substance: 20% in petrolatum <\/p>\n Component: 562-74-3 <\/p>\n human <\/p>\n Result: causes no sensitization <\/p>\n Repeated dose <\/p>\n toxicity(Component) <\/p>\n : Component: 98-55-5 <\/p>\n OralRat <\/p>\n NOEL: > 314 mg\/kg <\/p>\n Method: OECD Test Guideline 408 <\/p>\n Remarks: No adverse effect has been observed in chronic toxicity tests. <\/p>\n Component: 138-86-3 <\/p>\n Component: 586-62-9 <\/p>\n Carcinogenicity (Component) : <\/p>\n Pine Oil <\/b><\/p>\n Component: 562-74-3 Component: 98-55-5 <\/p>\n SECTION 12. Pine Oil \ufffd\ufffd\ufffd ECOLOGICAL INFORMATION <\/i><\/b><\/p>\n Component: <\/b><\/p>\n 98-55-5 alpha-TerpineolToxicity to fish: <\/p>\n semi-static test LC50 <\/p>\n Species: Brachydanio rerio (zebrafish) <\/p>\n Dose: 70 mg\/l <\/p>\n Exposure time: 96 h <\/p>\n Method: OECD Test Guideline 203 <\/p>\n Information taken from reference works and the <\/p>\n literature. <\/p>\n Toxicity to daphnia and other aquatic invertebrates: <\/p>\n static test EC50 <\/p>\n Species: Daphnia magna (Water flea) <\/p>\n Dose: 73 mg\/l <\/p>\n Exposure time: 48 h <\/p>\n Method: OECD Test Guideline 202 <\/p>\n Information taken from reference works and the <\/p>\n literature. <\/p>\n Toxicity to algae: <\/p>\n static testEC50 <\/p>\n Species: Pseudokirchneriella subcapitata (aglae) <\/p>\n Dose: 68 mg\/l <\/p>\n Exposure time: 72 h <\/p>\n Method: OECD Test Guideline 201 <\/p>\n Information taken from reference works and the <\/p>\n literature. <\/p>\n Toxicity to algae: <\/p>\n static testNOEC <\/p>\n Species: Pseudokirchneriella subcapitata (aglae)<\/p>\n Pine Oil <\/b><\/p>\n Dose: 3.9 mg\/l <\/p>\n Exposure time: 72 h <\/p>\n Method: OECD Test Guideline 201 <\/p>\n Information taken from reference works and the <\/p>\n literature. <\/p>\n Toxicity to bacteria: <\/p>\n static test NOEC <\/p>\n Species: activated sludge <\/p>\n Dose: 25.7 mg\/l <\/p>\n Method: OECD Test Guideline 310 <\/p>\n 138-86-3 Dipentene Toxicity to fish: <\/p>\n LC50 <\/p>\n Species: <\/p>\n Dose: 0.702 mg\/l <\/p>\n Exposure time: 96 h <\/p>\n 586-62-9 Terpinolene Toxicity to fish: <\/p>\n LC50 <\/p>\n Species: <\/p>\n Dose: 1.21 mg\/l <\/p>\n Exposure time: 96 h <\/p>\n Toxicity to daphnia and other aquatic invertebrates: <\/p>\n EC50 <\/p>\n Species: <\/p>\n Dose: 1.38 mg\/l <\/p>\n Exposure time: 48 h <\/p>\n Toxicity to daphnia and other aquatic invertebrates: <\/p>\n EC50 <\/p>\n Species: <\/p>\n Dose: 2.55 mg\/l <\/p>\n Exposure time: 48 h<\/p>\n Pine Oil <\/b><\/p>\n 562-74-3 4-Terpineol Toxicity to daphnia and other aquatic invertebrates: static test EC50 <\/p>\n Species: Daphnia magna (Water flea) <\/p>\n Dose: 97 mg\/l <\/p>\n Exposure time: 48 h <\/p>\n RIFM <\/p>\n SECTION 13. Pine Oil \ufffd\ufffd\ufffd DISPOSAL CONSIDERATIONS <\/i><\/b><\/p>\n Contaminated packaging : Place material into sealed containers and dispose of in accordance with local, state and federal regulations. <\/p>\n SECTION 14. TRANSPORT INFORMATION <\/i><\/b><\/p>\n DOT <\/b>Proper shipping name : Combustible liquid, n.o.s. (DIPENTENE) <\/p>\n UN number : 1993 <\/p>\n Class : CBL <\/p>\n Packing group : III <\/p>\n Emergency Response : 128 <\/p>\n Guidebook Number <\/p>\n DOT NON-BULK <\/b>Not dangerous goods <\/p>\n IATA <\/b>UN number : 3082 <\/p>\n Description of the goods : ENVIRONMENTALLY HAZARDOUS <\/p>\n SUBSTANCE, LIQUID, N.O.S. <\/p>\n (DIPENTENE) <\/p>\n Class : 9 <\/p>\n Packing group : III <\/p>\n ICAO-Labels : 9<\/p>\n Pine Oil <\/b><\/p>\n IMDG <\/b>UN number : 3082 <\/p>\n Description of the goods : ENVIRONMENTALLY HAZARDOUS <\/p>\n SUBSTANCE, LIQUID, N.O.S. <\/p>\n (DIPENTENE) <\/p>\n Class : 9 <\/p>\n Packing group : III <\/p>\n IMDG-Labels : 9 <\/p>\n EmSNumber 1 : F-A <\/p>\n EmSNumber 2 : S-F <\/p>\n Marine pollutant : yes <\/p>\n (DIPENTENE) <\/p>\n SECTION 15. REGULATORY INFORMATION<\/i><\/b><\/p>\n SARA 311\/312 Hazards <\/b>: Fire Hazard <\/p>\n Acute Health Hazard <\/p>\n Reportable Quantity <\/b>: <\/p>\n HMIS Classification <\/b>: Health hazard: 1 <\/p>\n Flammability: 2 <\/p>\n Physical and chemical hazards: 0 <\/p>\n SECTION 16. Pine Oil \ufffd\ufffd\ufffd OTHER INFORMATION <\/i><\/b><\/p>\n All reasonable efforts were exercised to compile this SDS in accordance with GHS SANS 10234. The SDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. RLS cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this SDS, RLS does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale <\/p>\n Disclaimer<\/strong>The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product\ufffd\ufffd\ufffds Add to Wishlist<\/p>\n Add to Wishlist<\/p>\n","protected":false},"excerpt":{"rendered":" Pine Oil<\/p>\n","protected":false},"featured_media":57819,"template":"","meta":{"content-type":""},"product_brand":[],"product_cat":[12335],"product_tag":[14444],"class_list":{"0":"post-65738","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-bulk-chemicals","7":"product_tag-pine-oil","9":"first","10":"instock","11":"shipping-taxable","12":"purchasable","13":"product-type-simple"},"jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=\/wp\/v2\/product\/65738","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=\/wp\/v2\/product"}],"about":[{"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=\/wp\/v2\/types\/product"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=\/wp\/v2\/media\/57819"}],"wp:attachment":[{"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=65738"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=%2Fwp%2Fv2%2Fproduct_brand&post=65738"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=%2Fwp%2Fv2%2Fproduct_cat&post=65738"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/hygienewaste.co.za\/index.php?rest_route=%2Fwp%2Fv2%2Fproduct_tag&post=65738"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}} |