Ethyl Acetate

Ethyl Acetate – Identification of Product
Chemical Code: CHE-E20
Chemical Name: Ethyl Acetate
Chemical Grade:
Chemical Formula: C₄H₈O₂
Chemical Weight: 88,11 g/mol
CAS No: 141-78-6
Chemical Synonyms: No Data Available

Ethyl Acetate – Hazards Identification
REACH No: 01-2119475103-46-XXXX
Signal Word: Danger
Supplemental Hazard Information: EUH066 – Repeated exposure may cause skin dryness or cracking.
Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Ethyl Acetate – Hazards statements
H225 – Highly flammable liquid and vapour.
H319 – Causes serious eye irritation.
H336 – May cause drowsiness or dizziness.

Ethyl Acetate – Precautionary statements
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378 – In case of fire: Use dry powder or dry sand to extinguish.
P403 + P235 – Store in a well-ventilated place. Keep cool.

Ethyl Acetate – Composition of Chemical
Chemical Formula: C₄H₈O₂
EC No 1272/2008: 01-2119475103-46-XXXX

First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Hazards Arising: No Data Available
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: Use water spray to cool unopened containers.

Accidental Release Measures
Personal Precautions: Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Method for Containment: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition – No
smoking.Take measures to prevent the build up of electrostatic charge.
Enviromental Precautions: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
Workers — Inhalation — Acute systemic effects — 1468 mg/m3
Workers — Inhalation — Acute local effects — 1468 mg/m3
Workers — Skin contact — Long-term systemic effects — 63 mg/kg BW/d
Workers — Inhalation — Long-term systemic effects — 734 mg/m3
Workers — Inhalation — Long-term local effects — 734 mg/m3
Consumers | Application Area | Exposure Routes | Health Effect | Value
Consumers — Inhalation — Acute local effects, Acute systemic effects — 734 mg/m3
Consumers — Skin contact — Long-term systemic effects — 37 mg/kg BW/d
Consumers — Inhalation — Long-term systemic effects — 367 mg/m3
Consumers — Ingestion — Long-term systemic effects — 4,5 mg/kg BW/
Consumers — Inhalation — Long-term local effects — 367 mg/m3
Predicted No Effect Concentration (PNEC)
Soil — 0,24 mg/kg
Marine water — 0,026 mg/l
Fresh water — 0,26 mg/l
Marine sediment — 0,125 mg/kg
Fresh water sediment — 1,25 mg/kg
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/Face Protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Splash contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm
Break through time: 113 min
Material tested: Butoject® (KCL 897 / Size M)
data source: KCL GmbH, D-36124 test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Colourless Liquid
Odour: No Data Available
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: Melting Point/Range: -84 °C
Boiling Point: 76,5 – 77,5 °C
Flash Point: -3,0 °C – Closed Cup
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 11,5 %(V) Lower explosion limit: 2,2 %(V)
Vapour pressure: 97,3 hPa at 20,0 °C
Vapour density: No Data Available
Relative density: 0,90 g/cm3 at 20 °C
Water solubility: Soluble
Partition Coefficien: Log Pow: 0,73
Auto-ignition Temperature: 427,0 °C
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: Surface tension 24,0 mN/m at 20,0 °C

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Heat, flames and sparks.
Incompatible Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Other decomposition products – No Data Available
Hazardous decomposition products formed under fire conditions. – Carbon oxides.

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – 5.620 mg/kg
LC50 Inhalation – Mouse – 2 h – 45.000 mg/m3
LD50 Dermal – Rabbit – > 18.000 mg/kg
Skin Corrosion/Irritation: Skin – Rabbit
Result: Mild skin irritation (OECD Test Guideline 404)
Serious Eye damage | Eye Irritation: Classified according to Regulation (EU) 1272/2008, Annex VI
Cell Mutagenicity: No Data Available
Carcinogenicity: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: May cause drowsiness or dizziness.
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: Toxicity to fish LC50 – Oncorhynchus mykiss (rainbow trout) – 350,00 – 600,00 mg/l – 96 h
LC50 – Pimephales promelas (fathead minnow) – 220,00 – 250,00 mg/l – 96 h
Toxicity to daphnia and other aquatic invertebrates
EC50 – Daphnia magna (Water flea) – 2.300,00 – 3.090,00 mg/l – 24 h
LC50 – Daphnia magna (Water flea) – 560 mg/l – 48 h
Toxicity to algae EC50 – Algae – 4.300,00 mg/l – 24 h
EC50 – SELENASTRUM – 1.800,00 – 3.200,00 mg/l – 72 h
Ecological Persistence and degradability: Biodegradability Result: 79 % – Readily biodegradable (OECD Test Guideline 301D)
Bioaccumulative Potential: Bio-accumulation – 3 d
Bio-concentration factor (BCF): 30
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: No Data Available

Disposal Considerations
Waste Treatment Methods: Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging
Dispose of as unused product

Transport Information
UN Number: ADR/RID: 1173
IMDG: 1173
IATA: 1173
UN Shipping Hazard: ADR/RID: ETHYL ACETATE
IMDG: ETHYL ACETATE
IATA: Ethyl acetate
Transport Hazard Class: ADR/RID: 3
IMDG: 3
IATA: 3
Packaging Group: ADR/RID: II
IMDG: II
IATA: II
Enviromental Hazards: ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special Precautions: No Data Available

Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: A Chemical Safety Assessment has been carried out for this substance.
Additional Info: RTECS: AH5425000
Inhalation of high concentrations may cause:, Headache, Drowsiness, Dizziness, Vomiting, narcosis, anemia, Central nervous system depression
Kidney – Irregularities – Based on Human Evidence.

Disclaimer

The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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